𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Substituent effects on the McLafferty rearrangement of ionized 2-(aryl)ethyl arylacetates

✍ Scribed by Jochanan Blum; Baruch Zinger; David Milstein; Ouri Buchman; Helmut Schwarz

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
170 KB
Volume
16
Category
Article
ISSN
1076-5174

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Substituent and Isotope Effects on the H
Substituent and Isotope Effects on the Hydrolysis Rates of 2-Aryl-2-diazocarboxylic Esters
✍ Mai-Huong Bui-Nguyen; Hans Dahn; John F. McGarrity πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 German βš– 625 KB

The overall kinetic solvent isotope effects on the acid catalyzed hydrolysis of a series of 2-aryl-2-diazocarboxylic esters ArCN2COOCH3, and one 2-aryl-2-diazocarboxamide C6H5CH2CON (CH,), vary inversely with the reactivity of the substrate, between limits of 3.14 and 1.46. A linear Hammett plot for

Substituent effects on the solvolysis of
Substituent effects on the solvolysis of 1,1-diphenyl-2,2,2-trifluoroethyl tosylates. Part III. Effects of electron-donating substituents in the fixed aryl moiety
✍ Mizue Fujio; Hyun-Joong Kim; Hiroshi Morimoto; Soo-Dong Yoh; Yuho Tsuno πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 190 KB πŸ‘ 1 views

The solvolysis rates of 1-aryl-1-(p-methoxyphenyl)-2,2,2-trifluoroethyl and 1-aryl-1-(p-phenoxyphenyl)-2,2,2-trifluoroethyl bromides and chlorides were conductimetrically measured at 25.0 Β°C in 80% aqueous ethanol. The solvolysis rates of 1-(p-methylphenyl)-fixed series were also set up to analyze t

Substituent effects on the 13C NMR spect
Substituent effects on the 13C NMR spectra of ethyl cis- and trans-2-(p-substituted-phenyl)-1-cyclopanecarboxylates
✍ Yoshiaki Kusuyama; Kenjiro Tokami πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 181 KB πŸ‘ 1 views

## Abstract ^13^C NMR spectra were measured for a series of ethyl __cis__‐ and __trans__‐2‐(__p__‐substituted ‐ phenyl) ‐ 1 ‐ cyclopropanecarboxylates. The effects of the __para__ substituents and the geometry on the chemical shifts are discussed.