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The thermochemical behavior of semibullvalenes. Annelation effects on the course of rearrangement

✍ Scribed by Leo A. Paquette; Ronald K. Russell; Robert E. Wingard Jr.

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
251 KB
Volume
14
Category
Article
ISSN
0040-4039

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The activation parameters [βˆ†G (200 K), βˆ†H , and βˆ†S ] for compounds, together with those for related compounds previously reported in the literature, show that conjugating the degenerate Cope rearrangements of barbaralane (1a) and several semibullvalenes (3a, 7a, 8a), and for those of a subsituents (