In the title complex, [Rh(acac)(CO)(PCy 2 Ph)] (acac = acetylacetonate, Cy = cyclohexyl) or [Rh(C 5 H 7 O 2 )(CO)-(C 18 H 27 P)], the Rh atom is coordinated by one P [Rh-P = 2.2424 (9) A ˚], two O [Rh-O = 2.0783 (17) and 2.0411 (18) A ˚] and one C [Rh-C = 1.797 (3) A ˚] atoms in a slightly distorted
(Acetylacetonato)carbonyl[diallyl(tert-butyl)phosphine]rhodium(I)
✍ Scribed by Ocando-Mavarez, Edgar ;Ascanio, Julián ;González, Teresa ;Atencio, Reinaldo ;Rosales, Merlín ;Silva, Ninoska
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 226 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Rh(C~5~H~7~O~2~)(C~18~H~21~P)(CO)], has the acetylacetonate-chelated Rh^I^ atom in a square-planar geometry. Intramolecular C—H...O hydrogen bonds exist between the acetylacetonate group and the cyclohexyl ring, resulting in a buckling of the acetylacetonate skeleton. Molecules
Molecules of the title compound, [Rh(C 9 H 6 NO)-{(C 14 H 21 O) 3 P}(CO)]Á0.5(CH 3 ) 2 CO, where (C 9 H 6 NO) = 8hydroxyquinolinato and {(C 14 H 21 O) 3 P} = tris(2,4-di-tert-butylphenyl)phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand -stacking distance of
Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10)