𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Carbon­yl(8-hydroxy­quinolinato)[tris­(2,4-di-tert-butyl­phen­yl)phosphite]rhodium(I) acetone hemisolvate

✍ Scribed by Janse van Rensburg, J. Marthinus ;Roodt, Andreas ;Muller, Alfred

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
204 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

Molecules of the title compound, [Rh(C 9 H 6 NO)-{(C 14 H 21 O) 3 P}(CO)]Á0.5(CH 3 ) 2 CO, where (C 9 H 6 NO) = 8hydroxyquinolinato and {(C 14 H 21 O) 3 P} = tris(2,4-di-tert-butylphenyl)phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand -stacking distance of 3.312 (1) A ˚. The effective cone angle (Â E ) for the phosphite ligand is 192 . The bidentate oxine ligand has a bite angle of 81.00 (8) and the Rh-P bond length is 2.1819 (6) A ˚.

📜 SIMILAR VOLUMES

Carbon­yl(8-hydroxy­quinolinato-κ2N,O)[t
Carbon­yl(8-hydroxy­quinolinato-κ2N,O)[tris­(2,3,4,5,6-penta­fluoro­phenyl)phosphine-κP]rhodium(I)
✍ Janse van Rensburg, J. Marthinus ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10)