𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Carbon­yl(8-hydroxy­quinolinato)[tris­(2-methyl­phen­yl) phosphite]rhodium(I)

✍ Scribed by Janse van Rensburg, J. Marthinus ;Roodt, Andreas ;Muller, Alfred ;Meijboom, Reinout

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
237 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Carbon­yl(8-hydroxy­quinolinato)[tris­(2
Carbon­yl(8-hydroxy­quinolinato)[tris­(2,4-di-tert-butyl­phen­yl)phosphite]rhodium(I) acetone hemisolvate
✍ Janse van Rensburg, J. Marthinus ;Roodt, Andreas ;Muller, Alfred 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 204 KB

Molecules of the title compound, [Rh(C 9 H 6 NO)-{(C 14 H 21 O) 3 P}(CO)]Á0.5(CH 3 ) 2 CO, where (C 9 H 6 NO) = 8hydroxyquinolinato and {(C 14 H 21 O) 3 P} = tris(2,4-di-tert-butylphenyl)phosphite, pack in a tail-to-tail fashion with an intermolecular quinoline ligand-to-ligand -stacking distance of

Carbon­yl(8-hydroxy­quinolinato-κ2N,O)[t
Carbon­yl(8-hydroxy­quinolinato-κ2N,O)[tris­(2,3,4,5,6-penta­fluoro­phenyl)phosphine-κP]rhodium(I)
✍ Janse van Rensburg, J. Marthinus ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10)

Synthesis of carbon-14 labelled cis-2-am
Synthesis of carbon-14 labelled cis-2-amino-1,9-dihydro-9-[4-(hydroxy-methyl)-2-cyclopenten-1-YL]-6H-purine-6-one; [8-14C]carbovir: A promising anti-aids drug
✍ M. B. Gopinathan; J. A. Kepler 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 French ⚖ 183 KB

The synthesis of the title compound (3) is described. Treatment of a solution of triethyl [14C]orthoformate in dry chloroform with cis-[4-(2,5-diamino-6-chloro-4-pyrimidinyl) -amino] -2cyclopentenyl]carbinol (1) afforded crude 2. Hydrolysis of crude 2 with 2 N sodium Eydroxide gave 3 in 34% overall