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(Acetylacetonato-κ2O,O′)carbonyl(cyclohexyldiphenylphosphine-κP)rhodium(I)

✍ Scribed by Brink, Alice ;Roodt, Andreas ;Visser, Hendrik G.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
700 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Rh(C~5~H~7~O~2~)(C~18~H~21~P)(CO)], has the acetylacetonate-chelated Rh^I^ atom in a square-planar geometry. Intramolecular C—H...O hydrogen bonds exist between the acetylacetonate group and the cyclohexyl ring, resulting in a buckling of the acetylacetonate skeleton. Molecules are packed in positions of least steric hindrance, with the phosphine ligands positioned above and below the Rh–acetylacetonate backbone.

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