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Chloridobis[2-(4-fluoroanilino)troponato-κ2N,O](triphenylphosphine-κP)rhodium(III)

✍ Scribed by Steyl, Gideon


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
433 KB
Volume
63
Category
Article
ISSN
1600-5368

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(2-Amino-4,5-dimethylbenzenesulfonato-κN
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The title compound, [Ag(C 8 H 10 NO 3 S)(C 18 H 15 P) 2 (H 2 O)], has a mononuclear structure, where the Ag I cation is fourcoordinated by two triphenylphosphine ligands, one water molecule and the N atom of a 2-amino-4,5-dimethylbenzenesulfonate anion in a distorted tetrahedral AgP 2 NO arrangement

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The title compound, [Nd(C~2~HCl~2~O~2~)~3~(C~10~H~8~N~2~)]~__n__~, was synthesized by reaction of neodymium(III) dichloroacetate with 2,2′-bipyridine in a water–ethanol (1:1) solution. The structure consists of chains running along the __a__ axis. The Nd^3+^ ions are coordinated by seven O and two N