l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 -bis[(2,2 0 0 0 -bipyridinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
(μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[(bipyridine-κ2N,N′)(triphenylphosphine-κP)copper(I)] bis(tetrafluoroborate)
✍ Scribed by Chen, Ji-Shu ;Liu, Pin-Hua ;Fu, Wen-Fu
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 868 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Di-4-pyridylethylenej 2 N:N 0 0 0 )bis[(bipyridine-j 2 N,N 0 0 0 )-(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
📜 SIMILAR VOLUMES
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
Di-l-acetato-j 4 O:O 0 0 0 -bis[bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )manganese(II)] bis(perchlorate)
The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff