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(μ-trans-1,2-Di-4-pyridylethylene-κ2N:N′)bis[(bipyridine-κ2N,N′)(triphenylphosphine-κP)copper(I)] bis(tetrafluoroborate)

✍ Scribed by Chen, Ji-Shu ;Liu, Pin-Hua ;Fu, Wen-Fu


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
868 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


Di-4-pyridylethylenej 2 N:N 0 0 0 )bis[(bipyridine-j 2 N,N 0 0 0 )-(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)


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{N,N′-Bis[3-(2-nitrophenyl)prop-2-enylid
✍ Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Lalegani, Arash ;Mokhtari, R 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 464 KB

The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff