✦ LIBER ✦

(Acetylacetonato)carbonyl(dicyclohexylphenylphosphine)rhodium(I)

✍ Scribed by Brink, Alice ;Roodt, Andreas ;Visser, Hendrik G.

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 215 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680604966x

No coin nor oath required. For personal study only.

✦ Synopsis

In the title complex, [Rh(acac)(CO)(PCy 2 Ph)] (acac = acetylacetonate, Cy = cyclohexyl) or [Rh(C 5 H 7 O 2 )(CO)-(C 18 H 27 P)], the Rh atom is coordinated by one P [Rh-P = 2.2424 (9) A ˚], two O [Rh-O = 2.0783 (17) and 2.0411 (18) A ˚] and one C [Rh-C = 1.797 (3) A ˚] atoms in a slightly distorted square-planar geometry. The bite angle O-Rh-O is 88.20 (6) and the calculated effective cone angle ( E ) for the dicyclohexylphenyl phosphine is 163 .

📜 SIMILAR VOLUMES

(Acetylacetonato)carbonyl[diallyl(te

(Acetylacetonato)carbonyl[diallyl(tert-butyl)phosphine]rhodium(I)

✍ Ocando-Mavarez, Edgar ;Ascanio, Julián ;González, Teresa ;Atencio, Reinaldo ;Ros 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 226 KB

(Acetylacetonato-κ2O,O′)carbonyl(cyclohe

(Acetylacetonato-κ2O,O′)carbonyl(cyclohexyldiphenylphosphine-κP)rhodium(I)

✍ Brink, Alice ;Roodt, Andreas ;Visser, Hendrik G. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 700 KB

The title compound, [Rh(C~5~H~7~O~2~)(C~18~H~21~P)(CO)], has the acetylacetonate-chelated Rh^I^ atom in a square-planar geometry. Intramolecular C—H...O hydrogen bonds exist between the acetylacetonate group and the cyclohexyl ring, resulting in a buckling of the acetylacetonate skeleton. Molecules

Mass spectrometric studies of acetylacet

Mass spectrometric studies of acetylacetonato (carbonyl) rhodium compounds

✍ Zhou Hua 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB

## OMS Letters Dear sir, The fragmntaticm of the three following carq?lexes has been studied: acetylacetonato (dicarbonyl) rhcdium Rh(o3) (acac) -1; acetylacetomto (triphenylphosphine) ( c a r h y l ) rhodium Rh(c0) (Pph,) (acac) -2; p h e n y l a ~~~~t c m a t o (dicarbonyl) rhodium Rh (03) 2 (ph

Carbonyl(8-hydroxyquinolinato-κ2N,O)[t

Carbonyl(8-hydroxyquinolinato-κ2N,O)[tris(2,3,4,5,6-pentafluorophenyl)phosphine-κP]rhodium(I)

✍ Janse van Rensburg, J. Marthinus ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10)

Carbonyl(triphenylarsine)(tropolonato

Carbonyl(triphenylarsine)(tropolonato)rhodium(I)

✍ Steyl, Gideon ;Roodt, Andreas 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 190 KB

Carbonyl(3,7-dichlorotropolonato)(trip

Carbonyl(3,7-dichlorotropolonato)(triphenylphosphine)rhodium(I)

✍ Steyl, Gideon 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 164 KB

The title compound, [Rh(C 7 H 3 Cl 2 O 2 )(C 18 H 15 P)(CO)], is a rhodium(I) derivative of chlorinated tropolonate. It crystallizes with a nearly square-planar geometry about the rhodium(I) metal centre. The most important bond distances and angles include: Rh-O(trans P) = 2.086 (2) A ˚, Rh-O(trans

(Acetyl­acetonato)carbon­yl(dicyclo­hexyl­phenyl­phosphine)rhodium(I)

✦ Synopsis

(Acetylacetonato)carbonyl(dicyclohexylphenylphosphine)rhodium(I)