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(Acetonitrile-κN)(3-amino-4-methylbenzenesulfonato-κN)aqua(triphenylphosphine-κP)silver(I) hemihydrate

✍ Scribed by Han, Jia-Jun ;Li, Ning

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
368 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ag(C~7~H~8~NO~3~S)(C~2~H~3~N)(C~18~H~15~P)(H~2~O)]·0.5H~2~O, has a mononuclear structure in which the Ag^I^ ion is four-coordinated by the N atoms from a 3-amino-4-methylbenzenesulfonate anion and an acetonitrile molecule, one P atom from a triphenylphosphine ligand and one O atom from a water molecule, forming a distorted tetrahedral configuration. Molecules are linked into a ribbon-like structure along the a axis by O(water)—H...O hydrogen bonds involving the coordinated water molecule, and N—H...O hydrogen bonds. The uncoordinated water molecule is disordered across an inversion centre.

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Single-crystal X-ray study T = 180 K Mean (C-C) = 0.007 A Some non-H atoms missing R factor = 0.045 wR factor = 0.131 Data-to-parameter ratio = 20.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.