(1,10-Phenanthroline-κ2N,N′)(triphenylphosphine-κP)silver(I) perchlorate acetonitrile hemisolvate
✍ Scribed by Khalaji, Aliakbar Dehno ;Amirnasr, Mehdi ;Daran, Jean-Claude
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 193 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 180 K Mean (C-C) = 0.007 A Some non-H atoms missing R factor = 0.045 wR factor = 0.131 Data-to-parameter ratio = 20.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
In the title compound, [Cu(C 18 H 12 N 2 )(C 18 H 15 P) 2 ]NO 3 Á-0.5C 18 H 12 N 2 Á0.5H 2 O, the Cu I atom adopts a distorted CuN 2 P 4 tetrahedral geometry.
The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.031 wR factor = 0.072 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.