The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.
(2,2′-Bipyridyl-κ2N,N′)nitrato(triphenylphosphine-κP)silver(I)
✍ Scribed by Amirnasr, Mehdi ;Welter, Richard ;Khalaji, Aliakbar Dehno
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 316 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 180 K Mean (C-C) = 0.007 A Some non-H atoms missing R factor = 0.045 wR factor = 0.131 Data-to-parameter ratio = 20.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Cu(C 18 H 12 N 2 )(C 18 H 15 P) 2 ]NO 3 Á-0.5C 18 H 12 N 2 Á0.5H 2 O, the Cu I atom adopts a distorted CuN 2 P 4 tetrahedral geometry.
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 -bis[(2,2 0 0 0 -bipyridinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
In the molecular title complex, [Ag(C~4~H~4~NO~2~)(C~10~H~8~N~2~)], the Ag atom adopts a distorted T-shaped AgN~3~ coordination. Aromatic π–π stacking interactions [centroid–centroid separation = 3.8393 (17) Å] lead to centrosymmetric dimers of molecules in the crystal structure.