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(2,2′-Biquinoline-κ2N,N′)bis(triphenylphosphine-κP)copper(I) nitrate 2,2′-biquinoline hemisolvate hemihydrate

✍ Scribed by Navarro, Maribel ;Corona, Oscar ;González, Teresa

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 341 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807011932

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✦ Synopsis

In the title compound, [Cu(C 18 H 12 N 2 )(C 18 H 15 P) 2 ]NO 3 Á-0.5C 18 H 12 N 2 Á0.5H 2 O, the Cu I atom adopts a distorted CuN 2 P 4 tetrahedral geometry.

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The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.

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Single-crystal X-ray study T = 180 K Mean (C-C) = 0.007 A Some non-H atoms missing R factor = 0.045 wR factor = 0.131 Data-to-parameter ratio = 20.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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(2,2′-Biquinoline-κ2N,N′)bis­(triphenyl­phosphine-κP)copper(I) nitrate 2,2′-biquinoline hemisolvate hemihydrate

✦ Synopsis

(2,2′-Biquinoline-κ2N,N′)bis(triphenylphosphine-κP)copper(I) nitrate 2,2′-biquinoline hemisolvate hemihydrate