(2-Methylbenzimidazolyl-κN)(triphenylphosphine-κP)gold(I) hemihydrate
✍ Scribed by Li, Dan ;Wu, Tao ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 168 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The dimeric title molecule, [Ag 2 Br 2 (C 2 H 3 N) 2 (C 18 H 15 P) 2 ], has crystallographic inversion symmetry. The two bridging AgÐ Br lengths are similar, at 2.7301 (6) and 2.7284 (7) A Ê .
The title compound, [Ag(C~7~H~8~NO~3~S)(C~2~H~3~N)(C~18~H~15~P)(H~2~O)]·0.5H~2~O, has a mononuclear structure in which the Ag^I^ ion is four-coordinated by the N atoms from a 3-amino-4-methylbenzenesulfonate anion and an acetonitrile molecule, one P atom from a triphenylphosphine ligand and one O at
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.031 wR factor = 0.072 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Cu(C 18 H 12 N 2 )(C 18 H 15 P) 2 ]NO 3 Á-0.5C 18 H 12 N 2 Á0.5H 2 O, the Cu I atom adopts a distorted CuN 2 P 4 tetrahedral geometry.