Iodo(1-methyl-2-mercaptoimidazole-κS)bis(triphenylphosphine-κP)copper(I)
✍ Scribed by Li, Dan ;Luo, Ya-Fang ;Wu, Tao ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 200 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The crystal structure of the title compound, [Cu(C 2 H 3 S 2 )-(C 18 H 15 P) 2 ]Á1.5C 7 H 8 , is reported. The compound is monomeric with the copper metal atom assuming a distorted tetrahedral geometry.
In the title compound, [Cu 2 I 2 (C 21 H 21 P) 3 ], one Cu I atom is coordinated by one tri-p-tolylphosphine and two iodide ligands in a distorted trigonal-planar geometry, whereas the other Cu I atom is coordinated by two phosphine and two iodide ligands in a distorted tetrahedral geometry.
The dimeric title molecule, [Ag 2 Br 2 (C 2 H 3 N) 2 (C 18 H 15 P) 2 ], has crystallographic inversion symmetry. The two bridging AgÐ Br lengths are similar, at 2.7301 (6) and 2.7284 (7) A Ê .