In the title complex, [Cu 2 I 2 (C 12 H 8 N 2 ) 2 ]ÁC 2 H 3 N, two Cu I atoms are bridged by two I atoms and each Cu I atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.
Di-μ-iodo-bis[(acetonitrile-κN)(triphenylphosphite-κP)copper(I)]
✍ Scribed by Näther, Christian ;Steinhoff, Tobias ;Jeß, Inke
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 349 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.023 wR factor = 0.060 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.066 wR factor = 0.131 Data-to-parameter ratio = 14.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The dimeric title molecule, [Ag 2 Br 2 (C 2 H 3 N) 2 (C 18 H 15 P) 2 ], has crystallographic inversion symmetry. The two bridging AgÐ Br lengths are similar, at 2.7301 (6) and 2.7284 (7) A Ê .
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.