Absolute rate constants for the reaction of silyl with nitric oxide, ethylene, propyne, and propylene, and the silyl recombination reaction
โ Scribed by S.K. Loh; D.B. Beach; J.M. Jasinski
- Book ID
- 107734726
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 858 KB
- Volume
- 169
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
Absolute rate constants hav-e been measured for the reaction of SiH, with N,O at temperatures between 295-747 K. The rate constantsarefittedto the Arrheniusequation: log( k/cm' molecule-' s-l) = ( -12.09+0.04) t (2.02?0.31) kJ mol-'JRTln IO. The data are plausibly consistent with a mechanism involv
Silylidyne, SiH, has been generated by excimer laser flash pbotolysis and its concentration monitored in real time by laserinduced fluorescence. Removal rates for SiH by hydrogen, deuterium and silane have been determined at 5 Torr total pressure in helium at ambient temperature. Silylidyne reacts g