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Absolute rate constants for the reaction of silyl with nitric oxide, ethylene, propyne, and propylene, and the silyl recombination reaction

โœ Scribed by S.K. Loh; D.B. Beach; J.M. Jasinski


Book ID
107734726
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
858 KB
Volume
169
Category
Article
ISSN
0009-2614

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Absolute rate constant and temperature d
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Absolute rate constants hav-e been measured for the reaction of SiH, with N,O at temperatures between 295-747 K. The rate constantsarefittedto the Arrheniusequation: log( k/cm' molecule-' s-l) = ( -12.09+0.04) t (2.02?0.31) kJ mol-'JRTln IO. The data are plausibly consistent with a mechanism involv

Absolute rate constants for the reaction
โœ M.H. Begemann; R.W. Dreyfus; J.M. Jasinski ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 455 KB

Silylidyne, SiH, has been generated by excimer laser flash pbotolysis and its concentration monitored in real time by laserinduced fluorescence. Removal rates for SiH by hydrogen, deuterium and silane have been determined at 5 Torr total pressure in helium at ambient temperature. Silylidyne reacts g