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Absolute rate constants for the reaction of SiH with hydrogen, deuterium and silane

✍ Scribed by M.H. Begemann; R.W. Dreyfus; J.M. Jasinski

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 455 KB
Volume: 155
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)87168-4

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✦ Synopsis

Silylidyne, SiH, has been generated by excimer laser flash pbotolysis and its concentration monitored in real time by laserinduced fluorescence. Removal rates for SiH by hydrogen, deuterium and silane have been determined at 5 Torr total pressure in helium at ambient temperature. Silylidyne reacts gas-kinetically with silane, but considerably more slowly with hydrogen and

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