Absolute rate constant, kinetic isotope effect and mechanism of the reaction of ethylene oxide with oxygen(3P) atoms
โ Scribed by Bogan, Denis J.; Hand, Clifford W.
- Book ID
- 120622130
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 963 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Earlier work on the reactions of O(^3^P) atoms with HCl and HBr has been extended by measuring rate constants for equation image A flowโtube method was used with chemiluminescent monitoring of the removal of atomic oxygen. Rate constants were measured at temperatures between 340 and 4
Absolute rate constants for the reaction OD + DNOJ have been determined at 297 + 2 K, using a pulsed laser photolysis-resonance absorption technique. The values (in cm3 mol-' s-l) obtained for DN03 alone and in the presence of 107 Torr SF, and at + 3a are (5.47 zb 0.75) x lo9 and (8.51+ 0.72) x lo9