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Absolute rate constant, kinetic isotope effect and mechanism of the reaction of ethylene oxide with oxygen(3P) atoms

โœ Scribed by Bogan, Denis J.; Hand, Clifford W.


Book ID
120622130
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
963 KB
Volume
82
Category
Article
ISSN
0022-3654

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## Abstract Earlier work on the reactions of O(^3^P) atoms with HCl and HBr has been extended by measuring rate constants for equation image A flowโ€tube method was used with chemiluminescent monitoring of the removal of atomic oxygen. Rate constants were measured at temperatures between 340 and 4

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Absolute rate constants for the reaction OD + DNOJ have been determined at 297 + 2 K, using a pulsed laser photolysis-resonance absorption technique. The values (in cm3 mol-' s-l) obtained for DN03 alone and in the presence of 107 Torr SF, and at + 3a are (5.47 zb 0.75) x lo9 and (8.51+ 0.72) x lo9