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Absolute rate constants of the elementary steps in the reaction of ethyliodide with 1-hexene and ethylene

✍ Scribed by V.Ya. Katsobashvilli; I.B. Afanas'yev


Book ID
118358740
Publisher
Elsevier Science
Year
1969
Weight
573 KB
Volume
11
Category
Article
ISSN
0032-3950

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Absolute rate constants for the reaction
✍ M.H. Begemann; R.W. Dreyfus; J.M. Jasinski πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 455 KB

Silylidyne, SiH, has been generated by excimer laser flash pbotolysis and its concentration monitored in real time by laserinduced fluorescence. Removal rates for SiH by hydrogen, deuterium and silane have been determined at 5 Torr total pressure in helium at ambient temperature. Silylidyne reacts g