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A novel interpenetrating 2-D brush-like structure: hydrothermal synthesis and crystal structure of [Cu(phen)V4O10]∞ (phen=1,10-phenanthroline)

✍ Scribed by Xiao-Bing Cui; Zhi-En Lin; Guo-Yu Yang


Book ID
114370663
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
206 KB
Volume
5
Category
Article
ISSN
1293-2558

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Hydrothermal Synthesis and Crystal Struc
✍ Yangguang Li; Enbo Wang; Hong Zhang; Guoyou Luan; Changwen Hu; Ninghai Hu; Hengq 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 426 KB

An organic+inorganic hybrid vanadium oxide [V V 4 O 10 (phen) 2 ] has been hydrothermally synthesized and structurally characterized by single-crystal X-ray di4raction. Red-brown crystals crystallize in the triclinic system, space group P1 , a ‫؍‬ 9.782( 2), b ‫؍‬ 6.5124( 14), c ‫؍‬ 19.765(4) A > ,

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,