Hydrothermal synthesis and crystal structure of organic–inorganic hybrid vanadate: [Zn(phen)(H2O)V2O6] (phen=1,10-phenanthroline)
✍ Scribed by Yanhui Chen; Xiaojun Gu; Jun Peng; Zhenyu Shi; Enbo Wang
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 206 KB
- Volume
- 692
- Category
- Article
- ISSN
- 0022-2860
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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
Two new organic-inorganic hybrid compounds, [Ga(phen)(H 1.5 PO 4 ) 2 ] Á H 2 O (1) and [Ga(phen)(HPO 4 )(H 2 PO 4 )] Á 1.5H 2 O (2) (phen ¼ 1,10-phenanthroline), have been synthesized by hydrothermal methods and structurally characterized by single-crystal X-ray diffraction, infrared spectroscopy, t
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