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A new reagent for the cleavage of the tertiary butyloxycarbonyl protecting group

✍ Scribed by A. Loffet; C. Dremier

Book ID
112699497
Publisher
Springer
Year
1971
Tongue
English
Weight
512 KB
Volume
27
Category
Article
ISSN
1420-682X

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πŸ“œ SIMILAR VOLUMES

Selective cleavage of the t-butyloxycarb
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## Abstract The value of several reagents capable of removing quantitatively the α‐amino protecting group of NPS‐aminoacyl‐ or peptidyl‐derivatives is assessed, by comparison with the reagents currently used, __i.e.__ hydrogen chloride, RS^–^‐nucleophiles or alkyl thioamides, especially with regard

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A new reagent for incorporating the 2-(1
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## A new reagent to incorporate the 2-(1adamantyl)-2-propyloxycarbonyl (Ad-POC) protecting group into amines, 2-(1-adamantyl)-2-propyl p-nitrophenylcarbonate, was prepared in two steps from the commercially available 1-adamantylcarbonyl chloride. The Ad-POC group was introduced into a variety of am