The structure of the title compound, [Cu~2~(C~5~H~5~NS)~2~Cl~2~(C~18~H~15~P)~2~], shows two independent molecules, each a dimer bridged through a Cu~2~S~2~ rectangular plane involving the two pyridinethione S atoms and lying about a centre of symmetry. The Cu atoms have a distorted tetrahedral geome
A dinuclear chloro(triphenylphosphito)copper(I) complex, di-μ2-chloro-bis[bis(triphenylphosphito)copper(I)]
✍ Scribed by Jian, Fang-Fang ;Wang, Ke-Fei ;Xiao, Hai-Lian ;Qiao, Yuan-Biao
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 230 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
A dinuclear chloro(triphenylphosphito)copper(I) complex, di-l 2 -chloro-bis[bis(triphenylphosphito)copper(I)]
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In the title compound, [CuBr(C 16 H 14 Cl 2 N 2 )(C 18 H 15 P)], the coordination polyhedron around the Cu I centre is approximately tetrahedral, distorted by the restricted bite angle of the chelating ligand. Intra-and intermolecular C-HÁ Á Á andstacking interactions are observed.
The binuclear copper(II) complex l-chlorol-methoxy-bis[chloro(di-2-pyridylamine)copper(II)]
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.035 wR factor = 0.110 Data-to-parameter ratio = 16.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.044 wR factor = 0.124 Data-to-parameter ratio = 15.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.