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Di-μ-pyridine-2-thiol­ato-bis­[chloro­(triphenyl­phosphine)copper(I)]

✍ Scribed by Marjani, Katayoun ;Davies, Sian C. ;Durrant, Marcus C. ;Hughes, David L. ;Khodamorad, Nejat

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
367 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The structure of the title compound, [Cu~2~(C~5~H~5~NS)~2~Cl~2~(C~18~H~15~P)~2~], shows two independent molecules, each a dimer bridged through a Cu~2~S~2~ rectangular plane involving the two pyridinethione S atoms and lying about a centre of symmetry. The Cu atoms have a distorted tetrahedral geometry. There is intramolecular hydrogen bonding between the pyridinium H atoms and the Cl ligands.

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