[N,N′-Bis(2-chlorobenzylidene)ethylenediamine]bromo(triphenylphosphine)copper(I)
✍ Scribed by Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Barati, Kazem ;Lee, Uk ;Choi, Jong-Ha
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 269 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [CuBr(C 16 H 14 Cl 2 N 2 )(C 18 H 15 P)], the coordination polyhedron around the Cu I centre is approximately tetrahedral, distorted by the restricted bite angle of the chelating ligand. Intra-and intermolecular C-HÁ Á Á andstacking interactions are observed.
📜 SIMILAR VOLUMES
{l-Bis [1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-j 2 N,N 0 0 0 }bis[iodo(triphenylphosphine-jP)copper(I)] acetonitrile disolvate
The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff
The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.