𝔖 Bobbio Scriptorium
✦   LIBER   ✦

[N,N′-Bis(2-chloro­benzyl­idene)ethyl­enediamine]bromo(triphenyl­phosphine)copper(I)

✍ Scribed by Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Barati, Kazem ;Lee, Uk ;Choi, Jong-Ha


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
269 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


In the title compound, [CuBr(C 16 H 14 Cl 2 N 2 )(C 18 H 15 P)], the coordination polyhedron around the Cu I centre is approximately tetrahedral, distorted by the restricted bite angle of the chelating ligand. Intra-and intermolecular C-HÁ Á Á andstacking interactions are observed.


📜 SIMILAR VOLUMES


{N,N′-Bis[3-(2-nitrophenyl)prop-2-enylid
✍ Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Lalegani, Arash ;Mokhtari, R 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 464 KB

The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff