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Azido{N,N′-bis[3-(2-nitrophenyl)prop-2-enylidene]ethylenediamine}(triphenylphosphine)copper(I) chloroform solvate

✍ Scribed by Habibi, Mohammad Hossein ;Lalegani, Arash ;Mokhtari, Reza ;Suzuki, Takayoshi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
591 KB
Volume
63
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

{N,N′-Bis[3-(2-nitrophenyl)prop-2-enylid
{N,N′-Bis[3-(2-nitrophenyl)prop-2-enylidene]ethylenediamine-κ2N,N′}chlorido(triphenylphosphine-κP)copper(I)
✍ Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Lalegani, Arash ;Mokhtari, R 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 464 KB

The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff

[N,N′-Bis(2-chloro­benzyl­idene)ethyl­en
[N,N′-Bis(2-chloro­benzyl­idene)ethyl­enediamine]bromo(triphenyl­phosphine)copper(I)
✍ Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Barati, Kazem ;Lee, Uk ;Choi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 269 KB

In the title compound, [CuBr(C 16 H 14 Cl 2 N 2 )(C 18 H 15 P)], the coordination polyhedron around the Cu I centre is approximately tetrahedral, distorted by the restricted bite angle of the chelating ligand. Intra-and intermolecular C-HÁ Á Á andstacking interactions are observed.

[N,N′-Bis(3-phenylprop-2-enylidene)ethyl
[N,N′-Bis(3-phenylprop-2-enylidene)ethylenediamine-κ2N,N′]bis(triphenylphosphine-κP)silver(I) nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate
✍ Khalaji, Aliakbar Dehno ;Amirnasr, Mehdi ;Schenk, Kurt J. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 467 KB

N,N 0 0 0 -Bis(3-phenylprop-2-enylidene)ethylenediamine-j 2 N,N 0 0 0 ]bis(triphenylphosphine-jP)silver(I) nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate