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[N,N′-Bis(3-phenylprop-2-enylidene)ethylenediamine-κ2N,N′]bis(triphenylphosphine-κP)silver(I) nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate

✍ Scribed by Khalaji, Aliakbar Dehno ;Amirnasr, Mehdi ;Schenk, Kurt J.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 467 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807022143

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✦ Synopsis

N,N 0 0 0 -Bis(3-phenylprop-2-enylidene)ethylenediamine-j 2 N,N 0 0 0 ]bis(triphenylphosphine-jP)silver(I) nitrate 1.36-acetonitrile 1.64-methanol 0.53-diethyl ether solvate

📜 SIMILAR VOLUMES

{N,N′-Bis[3-(2-nitrophenyl)prop-2-enylid

{N,N′-Bis[3-(2-nitrophenyl)prop-2-enylidene]ethylenediamine-κ2N,N′}chlorido(triphenylphosphine-κP)copper(I)

✍ Habibi, Mohammad Hossein ;Montazerozohori, Morteza ;Lalegani, Arash ;Mokhtari, R 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 464 KB

The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff