In the title compound, [CuBr(C 16 H 14 Cl 2 N 2 )(C 18 H 15 P)], the coordination polyhedron around the Cu I centre is approximately tetrahedral, distorted by the restricted bite angle of the chelating ligand. Intra-and intermolecular C-HÁ Á Á andstacking interactions are observed.
(Bromido)[N,N′-bis(2-nitrocinnamaldehyde)ethylenediamine](triphenylphosphine)copper(I)
✍ Scribed by Habibi, Mohammad Hossein ;Lalegani, Arash ;Mokhtari, Reza ;Suzuki, Takayoshi
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 580 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title complex, [CuCl(C 20 H 18 N 4 O 4 )(C 18 H 15 P)], has two molecules in the asymmetric unit. The Cu atom is fourcoordinate in a distorted tetrahedral geometry, bonded to two imine N atoms of the Schiff base, Cl and PPh 3 ; the main distortion is the small bite angle of the chelating Schiff
{N, prop-2-enylidene]ethylenediamine-2 N,N'}iodido(triphenylphosphane-P)copper(I)
The Cu I centre in the title compound, [Cu(C 14 H 14 N 2 )-(C 18 H 15 P) 2 ]ClO 4 , is covalently bonded to the P atoms of two triphenylphosphine ligands and to two N atoms of the Schiff base in a tetrahedral geometry.