In the title compound, [CuCl 2 (C 11 H 8 N 2 O) 2 ], the Cu II atom is coordinated by two N and two Cl atoms in a centrosymmetric square-planar geometry. Intermolecular NÐHÁ Á ÁCl hydrogen bonds link the molecules into a two-dimensional network.
Bis(2-methylbenzimidazole-κN1)copper(I) dichlorocuprate(I)
✍ Scribed by Goreshnik, Evgeny ;Schollmeyer, Dieter ;Mys'kiv, Marian
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 178 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.044 wR factor = 0.124 Data-to-parameter ratio = 15.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The title compound, [NiCl 2 (C 11 H 14 N 2 O) 2 ], was synthesized from 1-(2-ethoxyethyl)benzimidazole and nickel dichloride in ethanol and is isostructural with its cobalt analogue. It shows a distorted tetrahedral geometry about Ni II , involving two Cl atoms and two benzimidazole N atoms. The cry
metal-organic papers m1222 Sevim Tu È rktekin et al. [CoCl 2 (C 11 H 14 N 2 O) 2 ] Acta Cryst. (2004). E60, m1220±m1222
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.031 wR factor = 0.072 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.