Dichloro[2-(2-furyl)-1H-benzimidazole-κN3]copper(II)
✍ Scribed by Du, Gui-Xiang ;Li, Jun ;Zhang, Feng-Xing
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 171 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [CuCl 2 (C 11 H 8 N 2 O) 2 ], the Cu II atom is coordinated by two N and two Cl atoms in a centrosymmetric square-planar geometry. Intermolecular NÐHÁ Á ÁCl hydrogen bonds link the molecules into a two-dimensional network.
📜 SIMILAR VOLUMES
The title compound, [NiCl 2 (C 11 H 14 N 2 O) 2 ], was synthesized from 1-(2-ethoxyethyl)benzimidazole and nickel dichloride in ethanol and is isostructural with its cobalt analogue. It shows a distorted tetrahedral geometry about Ni II , involving two Cl atoms and two benzimidazole N atoms. The cry
metal-organic papers m1222 Sevim Tu È rktekin et al. [CoCl 2 (C 11 H 14 N 2 O) 2 ] Acta Cryst. (2004). E60, m1220±m1222
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.044 wR factor = 0.124 Data-to-parameter ratio = 15.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [CuCl~2~(C~4~H~6~N~2~)~3~], the Cu ion has a distorted trigonal–bipyramidal geometry of composition CuCl~2~N~3~. The Cu atom lies on a mirror plane.
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.021 wR factor = 0.052 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.