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4-Cyano-2-butenyl Group: A New Type of Protecting Group in Oligonucleotide Synthesis via Phosphoramidite Approach

โœ Scribed by Ravikumar, Vasulinga T.; Cheruvallath, Zacharia S.; Cole, Douglas L.

Book ID
127007250
Publisher
Taylor and Francis Group
Year
1997
Tongue
English
Weight
217 KB
Volume
16
Category
Article
ISSN
0732-8311

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4-Cyano-2-butenyl group: A new type of p
4-Cyano-2-butenyl group: A new type of protecting group in oligonucleotide synthesis via phosphoramidite approach
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4-Cyano-2-butenyl (CB) is a new type of protecting group for the intemucleotidic bonds in the synthesis of oligodeoxyribonucleotides by the phosphoramidite approach. This group is stable to acidic conditions and can be removed under mild conditions by a 8-elimination pathway using aqueous ammonium h

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Absbwct: 2-Diphenylmethylsilylethyl (DPSE) is a new protecting group for internucleotidic bonds in the synthesis of oligodeoqribo nucleotides by the phosphoramidite approach. This group is stable to acidic conditions and can be removed under mild /3$ragmentation conditions using aqueous ammonium hyd