The 3iP NMR spectrum of P&, in CS1 solution belongs to the AzX2 system (6 = 83.3 and 110.7 ppm respectively, downfield from D3P0,); this confirms the C\_ q,, symmetry of the free molecule. No P-S-P coupling is observed; this anomaly is discussed by comparison with related compounds.
โฆ LIBER โฆ
31P NMR spectra of P4S9 and P4S10: comparison with related compounds
โ Scribed by E.R. Andrew; W. Vennart; G. Bonnard; R.M. Croiset; M. Demarcq; E. Mathieu
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 389 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0009-2614
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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(CuI)(3)P(4)S(4) is obtained by reaction of stoichiometric amounts of CuI, P, and S in evacuated silica ampoules. The yellow compound consists of monomeric beta-P(4)S(4) cage molecules that are separated by hexagonal columns of CuI. (CuI)(3)P(4)S(4) crystallizes isotypic to (CuI)(3)P(4)Se(4) in the
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