Nb2Cl10(P4S10)2: A Co-Crystal of Nb2Cl10 and P4S10.
β Scribed by Arno Pfitzner; Diana Hoppe
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 9 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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An ampule reaction between Mo and PCl 5 at 200 Β°C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in MoΒ±PΒ±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Γ , Ξ± = 100.24(2), b = 95.55(2), c = 96.12(2)Β°(V = 559.3(2) A Γ 3