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31 P NMR study of P4S7

✍ Scribed by C. Brevard; M. Demarcq

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 229 KB
Volume: 82
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85130-5

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✦ Synopsis

The 3iP NMR spectrum of P&, in CS1 solution belongs to the AzX2 system (6 = 83.3 and 110.7 ppm respectively, downfield from D3P0,); this confirms the C_ q,, symmetry of the free molecule. No P-S-P coupling is observed; this anomaly is discussed by comparison with related compounds.

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