To a stirred solution of aluminium chloride (20 mmol) in dry tetrahydrofuran (100 ml), sodium azide (60 mmol) and 1-phenylsulfonyl-
3-Bromomethyl-1-phenylsulfonyl-1H-indole-2-carbonitrile
✍ Scribed by Palani, K. ;Ponnuswamy, M. N. ;Jaisankar, P. ;Srinivasan, P. C. ;Nethaji, M.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 225 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title molecule, C 16 H 11 BrN 2 O 2 S, the phenyl ring and mean plane of the indole ring system make a dihedral angle of 82.9 (1) . Intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules into linear chains extended along the a axis. The crystal packing is further stabilized by van der Waals forces.
📜 SIMILAR VOLUMES
The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.
In the title structure, C 16 H 10 N 2 O 3 S, there are two crystallographically independent molecules in the asymmetric unit. In one molecule, the dihedral angle between the indole ring system and the phenyl ring is 68.3 (2) , and in the other it is 80.3 (2) . C-HÁ Á ÁO, C-HÁ Á ÁN and C-HÁ Á Á inter
In the title molecule, C 17 H 14 BrNO 4 S, the methoxycarbonyl group is almost coplanar [dihedral angle = 5.89 ( 16) ] with the indole ring system, whereas the sulfonyl-bound phenyl ring is almost orthogonal to it [dihedral angle = 88.25 (6) ]. Weak C-HÁ Á ÁO, C-HÁ Á Á andinteractions link the molec