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3-Bromo-2-bromo­methyl-1-phenyl­sulfonyl-1H-indole

✍ Scribed by Sakthivel, P. ;Sethusankar, K. ;Sankar, P. Jai ;Joseph, P. S.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
160 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.014 A Ê R factor = 0.056 wR factor = 0.135 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, C 19 H 15 BrN 2 O 4 S, the orientations of the phenylsulfonyl and 2-bromo-4,5-dimethoxybenzyl substituents with respect to the indole moiety are influenced by intramolecular C-HÁ Á ÁO and C-HÁ Á ÁBr interactions. The sulfonyl-bound phenyl ring forms a dihedral angle of 86.9 (1