𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Methyl 2-bromo­methyl-1-phenyl­sulfonyl-1H-indole-3-carboxyl­ate

✍ Scribed by Senthil Kumar, G. ;Chinnakali, K. ;Ramesh, N. ;Mohanakrishnan, A. K. ;Fun, Hoong-Kun

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
402 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title molecule, C 17 H 14 BrNO 4 S, the methoxycarbonyl group is almost coplanar [dihedral angle = 5.89 ( 16) ] with the indole ring system, whereas the sulfonyl-bound phenyl ring is almost orthogonal to it [dihedral angle = 88.25 (6) ]. Weak C-HÁ Á ÁO, C-HÁ Á Á andinteractions link the molecules into a sheet parallel to the ab plane.

📜 SIMILAR VOLUMES

3-Bromo-2-bromo­methyl-1-phenyl­sulfonyl
3-Bromo-2-bromo­methyl-1-phenyl­sulfonyl-1H-indole
✍ Sakthivel, P. ;Sethusankar, K. ;Sankar, P. Jai ;Joseph, P. S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.

3-Bromo­methyl-1-phenyl­sulfonyl-1H-indo
3-Bromo­methyl-1-phenyl­sulfonyl-1H-indole-2-carbonitrile
✍ Palani, K. ;Ponnuswamy, M. N. ;Jaisankar, P. ;Srinivasan, P. C. ;Nethaji, M. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

In the title molecule, C 16 H 11 BrN 2 O 2 S, the phenyl ring and mean plane of the indole ring system make a dihedral angle of 82.9 (1) . Intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules into linear chains extended along the a axis. The crystal packing is further stabilized by van der Waa

2-Bromo-N-[3-bromo-1-(phenyl­sulfonyl)­i
2-Bromo-N-[3-bromo-1-(phenyl­sulfonyl)­indol-2-yl­methyl]-4-methyl­aniline
✍ Govind, M. M. ;Govindaraj, J. ;Rajakannan, V. ;Velmurugan, D. ;Kim, Moon-Jib ;Sr 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 208 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.014 A Ê R factor = 0.056 wR factor = 0.135 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

3-Benzyl-2-methyl-1-phenyl­sulfonyl-1H-i
3-Benzyl-2-methyl-1-phenyl­sulfonyl-1H-indole
✍ Malathy Sony, S. M. ;Palani, K. ;Charles, P. ;Ponnuswamy, M. N. ;Sureshbabu, N. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 236 KB
2-Methyl-1-phenyl­sulfonyl-1H-indole-3-c
2-Methyl-1-phenyl­sulfonyl-1H-indole-3-carbonitrile
✍ Sakthivel, P. ;Sethusankar, K. ;Jai Shankar, P. ;Joseph, P. S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 157 KB

To a stirred solution of aluminium chloride (20 mmol) in dry tetrahydrofuran (100 ml), sodium azide (60 mmol) and 1-phenylsulfonyl-