Bis{l:j 2 ,j 2 -6,6 0 0 0 -bis[2-(2-pyridyl)ethyliminomethyl]-2,2 0 0 0 -bipyridine}dicopper(I) bis(hexafluorophosphate)
(2,2′-Bipyridyl)dicarbonylbis(triethoxyphosphine-κP)rhenium(I) hexafluorophosphate
✍ Scribed by Blake, Alexander J. ;George, Michael W. ;Kuimova, Marina K. ;Williams, Colleen A. ;Wilson, Claire
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 158 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.
In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent