𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2-(2,5-Dimethyl­benz­yl)-3-phenyl­sulfan­yl-1-phenyl­sulfon­yl-1H-indole

✍ Scribed by Usha, G. ;Selvanayagam, S. ;Velmurugan, D. ;Ravikumar, K. ;Sureshbabu, N. ;Srinivasan, P. C.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
245 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, C 29 H 25 NO 2 S 2 , the benzene rings of the phenylsulfonyl and the dimethylbenzyl substituents are almost perpendicular to the indole unit, whereas the dihedral angle between the phenyl rings of the phenylsulfanyl and phenylsulfonyl groups is 71.2 (1) . The molecules in the crystal structure are held together by van der Waals, C-HÁ Á ÁO and C-HÁ Á ÁS interactions.

📜 SIMILAR VOLUMES

2,3-Dibenz­yl-1-(phenyl­sulfon­yl)-1H-in
2,3-Dibenz­yl-1-(phenyl­sulfon­yl)-1H-indole
✍ Rinderspacher, Alison ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 116 KB

In the crystal structure of the title compound, C 28 H 23 NO 2 S, the two benzyl groups are rotated in a such a way as to minimize their mutual interactions and their interaction with the phenylsulfonyl ring.

3-Bromo-2-(4-bromo-2,5-dimethoxy­benz­yl
3-Bromo-2-(4-bromo-2,5-dimethoxy­benz­yl)-1-phenyl­sulfon­yl-1H-indole
✍ Ravishankar, T. ;Chinnakali, K. ;Arumugam, N. ;Srinivasan, P. C. ;Usman, Anwar ; 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking int

2,3-Diiodo-1-(phenyl­sulfon­yl)-1H-indol
2,3-Diiodo-1-(phenyl­sulfon­yl)-1H-indole
✍ Rinderspacher, Alison ;Gribble, Gordon W. ;Butcher, Ray J. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 106 KB

In the title compound, C 14 H 9 I 2 NO 2 S, the two I atoms lie essentially in the plane of the indole ring and there is some iodine-iodine repulsion.

2,3-Diphenyl-1-(phenyl­sulfon­yl)indole
2,3-Diphenyl-1-(phenyl­sulfon­yl)indole
✍ Liu, Yanbing ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 177 KB

The crystal structure of the title compound, C 26 H 19 NO 2 S, reveals that the phenylsulfonyl ring and the adjacent phenyl ring are approximately syn-parallel to each other, with a dihedral angle of 18.4 (4) .