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2,3-Diiodo-1-(phenyl­sulfon­yl)-1H-indole

✍ Scribed by Rinderspacher, Alison ;Gribble, Gordon W. ;Butcher, Ray J. ;Jasinski, Jerry P.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
106 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 14 H 9 I 2 NO 2 S, the two I atoms lie essentially in the plane of the indole ring and there is some iodine-iodine repulsion.

📜 SIMILAR VOLUMES

2,3-Dibenz­yl-1-(phenyl­sulfon­yl)-1H-in
2,3-Dibenz­yl-1-(phenyl­sulfon­yl)-1H-indole
✍ Rinderspacher, Alison ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 116 KB

In the crystal structure of the title compound, C 28 H 23 NO 2 S, the two benzyl groups are rotated in a such a way as to minimize their mutual interactions and their interaction with the phenylsulfonyl ring.

3-Nitro-1-(phenyl­sulfon­yl)-1H-indole
3-Nitro-1-(phenyl­sulfon­yl)-1H-indole
✍ Roy, Sujata ;Pelkey, Erin T. ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 166 KB

The crystal structure of the title compound, C 14 H 10 N 2 O 4 S, confirms the position of the nitro group at position C-3 of the indole ring system. While the nitro group is coplanar with the indole ring system, the angle between the indole and phenyl planes is 83.9 (3) .

2,3-Diphenyl-1-(phenyl­sulfon­yl)indole
2,3-Diphenyl-1-(phenyl­sulfon­yl)indole
✍ Liu, Yanbing ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 177 KB

The crystal structure of the title compound, C 26 H 19 NO 2 S, reveals that the phenylsulfonyl ring and the adjacent phenyl ring are approximately syn-parallel to each other, with a dihedral angle of 18.4 (4) .

2-(2,5-Dimethyl­benz­yl)-3-phenyl­sulfan
2-(2,5-Dimethyl­benz­yl)-3-phenyl­sulfan­yl-1-phenyl­sulfon­yl-1H-indole
✍ Usha, G. ;Selvanayagam, S. ;Velmurugan, D. ;Ravikumar, K. ;Sureshbabu, N. ;Srini 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 245 KB

In the title compound, C 29 H 25 NO 2 S 2 , the benzene rings of the phenylsulfonyl and the dimethylbenzyl substituents are almost perpendicular to the indole unit, whereas the dihedral angle between the phenyl rings of the phenylsulfanyl and phenylsulfonyl groups is 71.2 (1) . The molecules in the

1-(Phenyl­sulfon­yl)-2,3-di-p-tolyl-1H-i
1-(Phenyl­sulfon­yl)-2,3-di-p-tolyl-1H-indole
✍ Liu, Yanbing ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 185 KB

The crystal structure of the title compound, C 28 H 23 NO 2 S, reveals that the phenylsulfonyl ring and the adjacent benzene ring are anti, with no evidence of stacking.