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3-Bromo-2-(4-bromo-2,5-dimethoxy­benz­yl)-1-phenyl­sulfon­yl-1H-indole

✍ Scribed by Ravishankar, T. ;Chinnakali, K. ;Arumugam, N. ;Srinivasan, P. C. ;Usman, Anwar ;Fun, Hoong-Kun

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
225 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking interactions involving the indole ring system link symmetry-related molecules into dimers.

📜 SIMILAR VOLUMES

3-Bromo-2-(2-bromo-4,5-dimethoxy­benz­yl
3-Bromo-2-(2-bromo-4,5-dimethoxy­benz­yl)-1-phenyl­sulfonyl-1H-indole
✍ Ravishankar, T. ;Chinnakali, K. ;Arumugam, N. ;Srinivasan, P. C. ;Usman, Anwar ; 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 439 KB

In the title compound, C 19 H 15 BrN 2 O 4 S, the orientations of the phenylsulfonyl and 2-bromo-4,5-dimethoxybenzyl substituents with respect to the indole moiety are influenced by intramolecular C-HÁ Á ÁO and C-HÁ Á ÁBr interactions. The sulfonyl-bound phenyl ring forms a dihedral angle of 86.9 (1

2-(2,5-Dimethyl­benz­yl)-3-phenyl­sulfan
2-(2,5-Dimethyl­benz­yl)-3-phenyl­sulfan­yl-1-phenyl­sulfon­yl-1H-indole
✍ Usha, G. ;Selvanayagam, S. ;Velmurugan, D. ;Ravikumar, K. ;Sureshbabu, N. ;Srini 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 245 KB

In the title compound, C 29 H 25 NO 2 S 2 , the benzene rings of the phenylsulfonyl and the dimethylbenzyl substituents are almost perpendicular to the indole unit, whereas the dihedral angle between the phenyl rings of the phenylsulfanyl and phenylsulfonyl groups is 71.2 (1) . The molecules in the

1-Bromo-3,4-bis­(bromo­meth­yl)-2,5-dime
1-Bromo-3,4-bis­(bromo­meth­yl)-2,5-dimethoxy­benzene
✍ Hammershøj, Peter ;Riis, Erik ;Christensen, Jørn B. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 242 KB

Dimethoxy-2,3-dimethylbenzene was brominated under radical conditions to give the title compound, C 10 H 11 Br 3 O 4 . The bond lengths and angles are generally within the normal ranges. The crystal packing is stabilized by weak intermolecular C-HÁ Á ÁO and C-HÁ Á ÁBr hydrogen bonds.

4-Bromo-N-(2-phenyl-1H-indol-7-yl)benzen
4-Bromo-N-(2-phenyl-1H-indol-7-yl)benzene­sulfon­amide
✍ Huang, Xiang-Hong ;Zhang, Qian-Feng ;Sung, Herman H. Y. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 247 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.043 wR factor = 0.108 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

2,3-Dibenz­yl-1-(phenyl­sulfon­yl)-1H-in
2,3-Dibenz­yl-1-(phenyl­sulfon­yl)-1H-indole
✍ Rinderspacher, Alison ;Gribble, Gordon W. ;Jasinski, Jerry P. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 116 KB

In the crystal structure of the title compound, C 28 H 23 NO 2 S, the two benzyl groups are rotated in a such a way as to minimize their mutual interactions and their interaction with the phenylsulfonyl ring.