In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking int
4-Bromo-N-(2-phenyl-1H-indol-7-yl)benzenesulfonamide
✍ Scribed by Huang, Xiang-Hong ;Zhang, Qian-Feng ;Sung, Herman H. Y.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 247 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.043 wR factor = 0.108 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The crystal packing in the title compound, C 15 H 16 N 2 O 2 S, consists of an NÐHÁ Á Á% pyrrole , a CÐHÁ Á Á% pyrrole , a CÐ HÁ Á Á% phenyl and two CÐHÁ Á ÁO interactions.
In the title molecule, C 22 H 18 N 4 O, all of the rings and the indole system are individually planar. In the crystal structure, molecules are linked by intermolecular N-HÁ Á ÁO hydrogen bonds, forming infinite chains running along the [001] direction.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.014 A Ê R factor = 0.056 wR factor = 0.135 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 39 H 42 BrNO 4 S 2 Si, the Si atom shows a tetrahedral geometry. The phenyl rings attached to the Si atom form a dihedral angle of 54.9 (1) . The molecular packing is stabilized by NÐHÁ Á ÁO hydrogen bonds.