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(1R,2S)-1-(6-Methoxy-2-naphthyl)-3-methyl-2-(p-methyl­phenyl­sulfonyl­amino)-­butan-1-ol

✍ Scribed by Li, Xingshu ;Jia, Xian ;Zhou, Zhongyuan


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
321 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.091 Data-to-parameter ratio = 18.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


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(1R,2S)-3-Methyl-2-(p-methyl­phenyl­sulf
✍ Li, Xingshu ;Jia, Xian ;Zhou, Zhongyuan 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 299 KB

Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.004 A Ê R factor = 0.045 wR factor = 0.089 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.002 A Ê Disorder in main residue R factor = 0.049 wR factor = 0.144 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, C 12 H 14 N 2 O 5 S 2 , the five ring atoms of the imidazolidine are nearly coplanar, the average deviation being 0.077 A ˚. The imidazolidine and benzene rings make a dihedral angle of 73.98 (10) . The crystal packing is stabilized by weak intermolecular C-HÁ Á ÁO hydrogen bo

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The ortho-disubstituted aromatic ring in the title compound, C 27 H 32 N 2 , is twisted by 76.1 (1) with respect to the isopropylsubstituted ring and by 89.3 (1) with respect to the methylsubstituted ring. The amino N atom is linked intramolecularly to the imino N by a hydrogen bond [NÁ Á ÁN = 2.686