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2-[2-(2,6-Di­methyl­phenyl­amino)­phenyl­methyl­ene­amino]-1,3-diiso­propyl­benzene

✍ Scribed by Gao, Haiyang ;Wu, Qing ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
176 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The ortho-disubstituted aromatic ring in the title compound, C 27 H 32 N 2 , is twisted by 76.1 (1) with respect to the isopropylsubstituted ring and by 89.3 (1) with respect to the methylsubstituted ring. The amino N atom is linked intramolecularly to the imino N by a hydrogen bond [NÁ Á ÁN = 2.686 (2) A Ê ].

📜 SIMILAR VOLUMES

5-Methyl-2-phenyl-4-[(Z)-(2-tolyl­amino)
5-Methyl-2-phenyl-4-[(Z)-(2-tolyl­amino)­phenyl­methyl­ene]­pyrazol-3(2H)-one
✍ Bao, Feng ;Lü, Xingqiang ;Wu, Qing ;Kang, Beisheng ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 186 KB

The NH unit on the exocyclic C C double bond in the title compound, C 24 H 21 N 3 O, lies on the same side of the double bond as the carbonyl unit of the pyrazolone ring, and the two interact through an NÐHÁ Á ÁO hydrogen bond [2.695 (2) A Ê ].