(1R*,2R*)-2-(Methylphenylamino)-1,2-dihydronaphthalen-1-ol–water (4/1)
✍ Scribed by Fagnou, Keith ;Lautens, Mark ;Lough, Alan J.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 381 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 17 H 21 NO 2 , there are two chiral C atoms. There are two intramolecular hydrogen bonds and one intermolecular hydrogen bond. The latter intermolecular hydrogen bond links the molecules in a helical fashion along the b-axis direction.
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.004 A Ê R factor = 0.045 wR factor = 0.089 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The molecule of the title compound, C 18 H 15 NO 2 , is not completely planar. It adopts a keto±amine tautomeric form with an intramolecular NÐHÁ Á ÁO and an intermolecular OÐ HÁ Á ÁO hydrogen bond. The molecules are linked by OÐ HÁ Á ÁO hydrogen bonds into a three-dimensional network.
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.005 A Ê R factor = 0.045 wR factor = 0.091 Data-to-parameter ratio = 18.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.