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S-(4-Methoxy­phenyl) 3-methyl­sulfonyl-2-oxoimidazolidine-1-carbo­thio­ate

✍ Scribed by Feng, Wen ;Wu, Xue-Ping ;Su, Wei-Ke

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
297 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 12 H 14 N 2 O 5 S 2 , the five ring atoms of the imidazolidine are nearly coplanar, the average deviation being 0.077 A ˚. The imidazolidine and benzene rings make a dihedral angle of 73.98 (10) . The crystal packing is stabilized by weak intermolecular C-HÁ Á ÁO hydrogen bonds.

📜 SIMILAR VOLUMES

S-p-Tolyl 3-methane­sulfonyl-2-oxoimidaz
S-p-Tolyl 3-methane­sulfonyl-2-oxoimidazolidine-1-carbo­thio­ate
✍ Liang, Xian-Rui ;Chen, Jian-Hua ;Feng, Wen ;Su, Wei-Ke ;Chen, Wei-Rong 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 263 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.047 wR factor = 0.116 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Methyl 2-bromo­methyl-1-phenyl­sulfonyl-
Methyl 2-bromo­methyl-1-phenyl­sulfonyl-1H-indole-3-carboxyl­ate
✍ Senthil Kumar, G. ;Chinnakali, K. ;Ramesh, N. ;Mohanakrishnan, A. K. ;Fun, Hoong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 402 KB

In the title molecule, C 17 H 14 BrNO 4 S, the methoxycarbonyl group is almost coplanar [dihedral angle = 5.89 ( 16) ] with the indole ring system, whereas the sulfonyl-bound phenyl ring is almost orthogonal to it [dihedral angle = 88.25 (6) ]. Weak C-HÁ Á ÁO, C-HÁ Á Á andinteractions link the molec