(1,4-Diazacycloheptane-κ2N,N′)(2-thioxo-1,3-dithiole-4,5-dithiolato-κ2S4,S5)nickel(II)
✍ Scribed by Wen, Yi-Hang ;Zhang, Qi-Wei
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 227 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title ion-pair compound, (C 12 H 12 N)[Ni(C 3 S 5 ) 2 ], the Ni III atom exhibits a square-planar coordination geometry with four S atoms of the two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands. Some weak SÁ Á ÁS interactions are found.
In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.
In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror sy