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1,3-Migration of triorganosilyl groups from carbon to oxygen in highly crowded organosilanols

✍ Scribed by Abdulrahman I. Al-Mansour; Mohammed A.M.R. Al-Gurashi; Colin Eaborn; Faraedon A. Fattah; Paul D. Lickiss

Book ID
107811780
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
433 KB
Volume
393
Category
Article
ISSN
0022-328X

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Reversible 1,4 migration of a silyl grou
Reversible 1,4 migration of a silyl group from oxygen to carbon: an unexpected route to Ξ±-trialkylsilyl ketoximes
✍ J. Mora; A. Costa πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 203 KB

## Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group. After protonation, the resulting a-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.