๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Migration of Silicon from Oxygen to Carbon in O-Trialkylsilyl Ketene Acetals

โœ Scribed by Raucher, Stanley; Schindele, Deborah C.


Book ID
121331822
Publisher
Taylor and Francis Group
Year
1987
Tongue
English
Weight
267 KB
Volume
17
Category
Article
ISSN
0039-7911

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Reversible 1,4 migration of a silyl grou
โœ J. Mora; A. Costa ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

## Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group. After protonation, the resulting a-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.